Kinda, but not really. Deuterium exists naturally in more or less the ratio as it has since the solar system first coalesced.
Also, deuterium is a component of heavy water, but the term "deuterium" actually referred to the specific isotope of hydrogen where the nucleus consists of one proton and one neutron, as opposed to a single proton (which is the more common isotope)
Autoionization and the reverse reaction are constantly happening in water, and when the reaction is happening at the same rate forward and backward the system is said to be "at dynamic equilibrium" (aka, stuff is happening, but there's no net change)
In pure water, the equilibrium concentration of hydronium and hydroxide are equal, so it's said to be neutral. At room temperature, that equilibrium concentration is approximately 1*10^-7 moles per liter, which gives a pH of 7 (since pH is defined as the negative log _10 of hydronium concentration)