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A big part of it was scientific illiteracy. There was talk at the time about "protecting the prison officers from exposure to the gas".
They were treating it like a poison.
Which adds stupidity to the malice.
Assuming that "concern" was in good faith in the first place. I believe it was a bad faith pretext for not venting the gas because it's a well known fact that nitrogen makes up a significant portion of the atmosphere. If they were really worried about the nitrogen displacing enough oxygen to be dangerous, I can think of several ways to eliminate that risk even if I play along and accept that it's possible.
Instead they went with the stupidest and most cruel option. Make sure there's no ventilation on the mask, and that it had a tight seal before turning on the gas. A gas they were treating like a deadly poison.
And since there was no ventilation at all, there was no gas flow. There was no oxygen displacement. Just the CO2 buildup.