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I think its common to think about these min-max scenarios about squeezing every bit of efficiency out of a solar system deployment. I encourage others to go down this through process, but don't get too discouraged at the end when you start looking about why this gets really complicated really quickly.
In your example of trying to bypass the PC power supply and feed DC power directly to the PC, I can think of a number of challenges to that working (or being reliable).
Even if you're avoiding the switch from DC to AC and then back to DC inside the computer, that does nothing to step down the voltage produced by the panels. In a PC you need the following voltages 3.3V, 5V, 5Vsb, -12V, and +12V. On a PV solar system, you'd get anywhere from 18v on a single small panel, to 60v on a large panel, to 400v on a whole residential array.
Just because the panels are producing DC doesn't mean its necessarily clean. DC just means the current flow never switches direction. Lets say you set up a whole bunch of buck converters to produce all the right voltages to feed an ATX power supply. What happens when you get a cloud shadow moving across the array and the power produced drops for a few seconds? PCs are expecting very clean, very predictable power. That voltage sag would likely be enough to interrupt the operation of the PC.
Would it be possible to engineer a high quality power supply with enough capacitance and batteries to provide clean power from solar? Sure, but that's a pretty complicated engineering exercise. You've already go two very well designed power systems: the inverter(s) from your array and your PC power supply. The only cost is 3% DC to AC conversion loss.
Unless you constantly want to be messing with your solar deployment, you quickly realize that reliability is usually the state to optimize for. Get your system working at a decent expected state that will stay working without intervention for a long long time. Optimize elsewhere.
Thanks for taking the time to reply :)
The idea is that you would use the 48v off of the battery array, the charge controller side takes care of dealing with the fluctuating power from the panels and the linked DC power supply handles the conversion from the 48v output of the battery to the various voltages required by the PC.
Same with the supply voltage drops, the battery is providing the stability and so major voltage swings are unlikely.
You're right that it is a tiny increases in efficiency. A 3% conversion loss on the inverters and a 5-10% loss on the AC to DC conversion isn't anything major, it'd only add about 5-10 minutes of battery life across a day (not counting the cooling costs of the heat conversion due to the increased inefficiencies).
This is mostly a quest for niche gadgets and a way to explore/lean the technology. I would almost certainly start with a bog standard solar battery setup.