this post was submitted on 17 Jul 2026
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[–] FiniteBanjo@feddit.online 30 points 1 day ago (3 children)

They threw balloons over the fence to weaken concrete with Salt, Acetic Acid, Peroxide, and acrylic paint at some bare concrete and steel where a facility is going to be built.

I feel like the guy with the paint didn't understand the memo.

[–] CADmonkey@lemmy.world 4 points 21 hours ago (2 children)

Sugar water would have worked better.

[–] perviouslyiner@lemmy.world 4 points 19 hours ago* (last edited 18 hours ago) (1 children)

Just needs a supply of ~~Dioxygen difluoride~~ Chlorine trifluoride [ref] which when spilled in large quantities "burned its way through a foot of concrete floor and chewed up another meter of sand and gravel beneath"

[–] CADmonkey@lemmy.world 5 points 19 hours ago (1 children)

A quick visit to wikipedia gives me this lovely paragraph which makes me nervous:

The other main property of this unstable compound is it's oxidizing power, although most experimental reactions have been conducted near -100 °C (173 K). Several experiments with the compound resulted in a series of fires and explosions. Some of the compounds that produced violent reactions with O~2~F~2~ include ethyl alcohol, methane, ammonia, and even water ice.

Flourine is really scary stuff. If we're going to toss some FOOF at the concrete, we could also use ClF~3~. Clorine Triflouride is another angry oxidizer that I'm pretty sure is hypergolic with sand of all things.

[–] FiniteBanjo@feddit.online 5 points 16 hours ago

More like tossing FAFO

badum'tsh

[–] fullsquare@awful.systems 4 points 20 hours ago (2 children)

there are also more damage-susceptible things in a datacenter

[–] CADmonkey@lemmy.world 5 points 19 hours ago

Oh definitely. I was just speaking on concrete.

[–] FiniteBanjo@feddit.online 2 points 16 hours ago

Walls aren't up yet, just an empty foundation and some steel beams.

[–] KairuByte@lemmy.world 20 points 1 day ago (1 children)

I feel like none of these things will actually weaken concrete, unless it’s being added to the concrete mix itself.

[–] FiniteBanjo@feddit.online 26 points 1 day ago (2 children)

The concrete is actually highly acidic but the outer layer cures to become alkaline and the two layers together end up becoming water resistant, so by adding acid to the surface it can lose its water repellent capability and weaken faster.

If the concrete were sealed with a wax or an acrylic then Acetone would also be effective.

[–] fullsquare@awful.systems 7 points 1 day ago (1 children)

concrete is calcium carbonate and silicate, both are basic. it's also slightly porous but mostly waterproof by itself, doesn't matter that hard in this application since there will be AC removing water from the inside 24/7 anyway

[–] FiniteBanjo@feddit.online 1 points 21 hours ago (1 children)

Carbonation causes acidity and the traditional methods of creating concrete involves furnaces which introduce various forms of carbonation. The Calcium Carbonate once dissolved in water will start to form the Calcium Hydroxide layer on the surface, thats the alkaline layer, and deeper in the carbonation creates acidity.

[–] fullsquare@awful.systems 0 points 20 hours ago (1 children)

calcium carbonate is still basic and even hydrogen carbonate is basic enough to be protective against steel corrosion

The Calcium Carbonate once dissolved in water will start to form the Calcium Hydroxide layer on the surface, thats the alkaline layer, and deeper in the carbonation creates acidity.

100% wrong, how come there's more carbon dioxide inside than outside, you're starting from calcium hydroxide and silicate. on the surface there's some carbonate formation from carbon dioxide, but when it can't get there calcium silicate forms instead. either way both are basic

[–] FiniteBanjo@feddit.online 0 points 17 hours ago (1 children)

Well, now you're contradicting yourself from earlier when you stated we were discussing Calcium Carbonate and Silicate.

The Calcium Carbonate degrades into Calcium Oxide. Calcium Oxide will form Calcium Hydroxide on the cured surface.

The only reliable way to seperate the Calcium from the oxidation afaik would be the introduction of Chlorine, so you're definitely not seeing the reverse happening regardless of how much carbon dioxide there is.

[–] fullsquare@awful.systems 0 points 13 hours ago (1 children)

you see, you can be as wrong as you want to be. i won't be teaching you middle school level chemistry against your will in a comment section. in concrete Ca2+ remains Ca2+, be it as hydroxide or carbonate or silicate and it cannot become reduced in normal concrete conditions and definitely it can't be oxidized.

The Calcium Carbonate degrades into Calcium Oxide

no it fucking doesn't, this is what happens when cement is prepared in a kiln. near surface of curing concrete calcium hydroxide captures carbon dioxide from air, then this crust of precipitate blocks it from moving deeper. which is why the rest of calcium hydroxide reacts with silica forming calcium silicate, which takes more time and is responsible for late strengthening. before you lost plot i was talking about oxidation of steel rebar, and it depends on many things, but for regular carbon steel if there's no oxygen then it's much slower. and because concrete is not very permeable to oxygen, there are all these engineering requirements about how deep rebar has to be. anyway, a little bit of vinegar would be just neutralized by calcium hydroxide from concrete and won't do anything, a little bit of salt would be diluted massively and also won't do anything, hydrogen peroxide would decompose because anything will do that

[–] FiniteBanjo@feddit.online 0 points 11 hours ago

You can make it happen faster in a furnace but it will happen regardless.

[–] KairuByte@lemmy.world 9 points 1 day ago (3 children)

Oh really? I honestly never considered that possibility and always thought of concrete as a kind of inert “stone,” I find this legitimately interesting.

[–] RIotingPacifist@lemmy.world 21 points 1 day ago (2 children)

My understanding is that the genius of such attacks is they don't actually have to do the damage but if there's the fear of chemical damage you don't want to build the rest of a building on top of it.

[–] CADmonkey@lemmy.world 10 points 21 hours ago

This right here is the answer. The possibility that the concrete cure was all or partially disrupted can mean the concrete has to go away and be re-poured.

[–] snooggums@piefed.world 7 points 22 hours ago

That would be a great reason to announce the damage as well, which they did.

[–] Maestro@fedia.io 8 points 1 day ago

Check out the Hoover Dam. It's concrete is still curing to this day!

[–] TheOctonaut@piefed.zip 3 points 1 day ago

Stone itself isn't inert either?

[–] fullsquare@awful.systems 3 points 1 day ago (1 children)

these things can corrode rebar slightly

[–] FiniteBanjo@feddit.online 2 points 21 hours ago (1 children)

Only if it is uncoated iron rebar. There are also coated rebar, galvanized rebar, stainless steel rebar, or fiberglass rebar.

Iron is the most popular rebar among workers for its ability to be shaped by hand and easily cut, but it's lacking in longevity due to its chemical vulnerability.

Galvanized is also weak to chemical attacks but from Alkaline attacks.

[–] fullsquare@awful.systems 2 points 20 hours ago

coated rebar isn't, it'll always get dinged somewhere. stainless is expensive and the real available scalable option is either galvanized or sometimes basalt fiber, or glass fiber but i've not heard about it too much. the most important factor in slowing down corrosion is how thick concrete layer is on top of rebar, because concrete is very slightly porous and will let oxygen in, but the thicker that layer is, the slower oxygen gets to rebar, then the slower corrosion is, and this means it takes longer for rust layer to grow enough for concrete around rebar to fail due to swelling, because rust takes more volume than corroding steel

a bit of vinegar might strip zinc layer, but won't do too much and definitely it won't matter long term until most of zinc layer is gone. salt also promotes corrosion but this also depends on oxygen availability and won't be too fast, it would only matter if there's salt in concrete in large amounts